Gekijouban NARUTO: Shippuuden - Kizuna
Episode 81
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A mysterious group of ninjas makes a surprise attack on the Konohagakure, which takes great damage. The nightmare of another Shinobi World War could become a reality. Sasuke, who left Konoha to kill his brother, Itachi, appears for the second time in front of Naruto at an unknown location to prevent it from coming to fruition. (Source: Wikipedia)
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